Yes -- I'm aware of her experience level as you stated. That is why I posted starting and average salaries. But also look at the ad you posted:
Salary Placement Commensurate with experience $33,648 - $67,296
Maximum salary placement step 9 for new hires
And as I said, realize that is a range...if you don't believe me about that being the top of the range and being likely 20+ years of experience, that's fine (realize though, that while pursuing a job as a teacher, I have literally read THOUSANDS of these ads, and have responded to dozens of them, and in every case, was told that the salary range reflected all positions in the ad, and that the top salary was the top of the range). Look at the ad then. It says max salary placement = step 9. Even if you believe that the $67K is for step 9, your friend should not be at step 9 after 5 years with a B.S. She should be at step 5, step 6 tops.
If she does make that much money (and Ender, don't misunderstand me here - I'm not accusing you of lying, I'm sure she does make that as you said - I'm just saying it's not a normal representative figure in my experience), and if there are many others like her, than Cali is not a very good representative example of the nation as a whole. Most teachers have to work at least 10-15 years to make the kind of money you're friend is making with a B.S./B.A. - if they get an advanced degree, perhaps they can cut that down to 8-10. And I'm talking about historically high paying states like NJ, CT, PA, and VA -- not states like AK, MS, or LA, where a teacher will likely never make that much, regardless of time in, due to the lower cost of living. Realize also that in the private sector, with jobs that require a bachelors degree, the salary level to experience level ratio is about the same, if not lower for the teachers (think what a web designer with 10 years experience makes vs. teachers in the area).
If she does make that, maybe she is in a special demand position, and/or works in an area with a very high cost of living, or has some other special situation with her district. I hope you are right though -- if teachers in Cali make that after 5 yrs, I'm seriously considering moving there. As if the constant sunshine and Gracie Academy weren't enough, a higher salary would very much sweeten the deal.
And as for the VP, realize that he is not a teacher with classroom duties -- he is an administrator, with completely different responsibilities and criteria for his job. Again, think about what is done in the private sector. It is all a matter of supply and demand, as well as society's perceived worth of a profession. When I worked for an Internet company, I pulled in close to 70K, and the project managers above me made between 100 and 110K. My teaching job was infinitely harder than my Internet one (not to mention more important, as I didn't hold children's futures in my hand when supervising web page design), and the PM's above me had a MUCH easier job than any VP I've ever met. Part of the proof of this is the fact that even at 110K+ for VP's, most districts have problems filling the job and keeping people, because the job sucks and nobody wants it.